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  • Heterocyclic compounds with metal hetero atoms

    From Peter Percival@21:1/5 to All on Tue Jan 14 10:33:22 2020
    Are there heterocyclic compounds with transition metal heteroatoms? I
    am aware of heterocyclic compounds with bismuth and tin heteroatoms, but
    I'm wondering of there are "more metallic" (so to speak) examples.

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  • From Martin Brown@21:1/5 to Peter Percival on Tue Jan 14 12:51:59 2020
    On 14/01/2020 10:33, Peter Percival wrote:
    Are there heterocyclic compounds with transition metal heteroatoms?  I
    am aware of heterocyclic compounds with bismuth and tin heteroatoms, but
    I'm wondering of there are "more metallic" (so to speak) examples.

    Will copper do?

    https://www.sciencedirect.com/science/article/pii/S0022328X18300718

    --
    Regards,
    Martin Brown

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  • From Peter Percival@21:1/5 to Martin Brown on Tue Jan 14 16:37:26 2020
    Martin Brown wrote:
    On 14/01/2020 10:33, Peter Percival wrote:
    Are there heterocyclic compounds with transition metal heteroatoms?  I
    am aware of heterocyclic compounds with bismuth and tin heteroatoms,
    but I'm wondering of there are "more metallic" (so to speak) examples.

    Will copper do?

    https://www.sciencedirect.com/science/article/pii/S0022328X18300718


    Thank you.

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  • From Frank <"frank@21:1/5 to Peter Percival on Tue Jan 14 19:05:44 2020
    On 1/14/2020 11:37 AM, Peter Percival wrote:
    Martin Brown wrote:
    On 14/01/2020 10:33, Peter Percival wrote:
    Are there heterocyclic compounds with transition metal heteroatoms?
    I am aware of heterocyclic compounds with bismuth and tin
    heteroatoms, but I'm wondering of there are "more metallic" (so to
    speak) examples.

    Will copper do?

    https://www.sciencedirect.com/science/article/pii/S0022328X18300718


    Thank you.

    There are also metal phthalocyanines. Iron and copper are mentioned:

    https://en.wikipedia.org/wiki/Phthalocyanine

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